Magnetic properties of the core CX21 off the Yangtze Estuary and its influencing factors
-
摘要: 以长江口外、长340 cm的CX21柱样为对象,在磁性特征、地球化学和粒度分析的基础上,结合前期对Y7柱样的研究,探讨粒度、早期成岩作用和物源变化对沉积物磁性特征的影响.研究结果表明,该柱样磁性特征和粒度垂向变化显著.磁性参数、SIRM、fd和fd%与 2~4 m、4~8 m粒级含量呈相对较弱的正相关, 而ARM、ARM/SIRM和ARM/与16 m以下的各细颗粒组分有较强的正相关,表明CX21柱样沉积物磁性特征受到粒度变化的影响.利用BCR方法进行的铁的形态分析结果表明,CX21柱样170 cm深度以下具有较强的还原环境,磁性矿物受到较强的早期成岩作用影响.氧化还原不敏感元素Ti的垂向变化指示了物源变化,Ti向表层的增加与和SIRM向表层的增强具有同步性,说明物源变化也是CX21沉积物磁性特征影响的重要因素.尽管粒度组成和沉积速率不同,CX21与Y7柱样的磁性特征在垂向上具有相似性,表明磁性特征可作为长江口外沉积物地层对比的工具之一.Abstract: Core CX21(12230 E,3000 N) is 340 cm in length, obtained off the Yangtze Estuary, China. In this study, magnetic, geochemical and particle size analyses were conducted on sediments from the core CX21 to determine the major factors (including early diagenesis, particle size and sediment provenance) that control the down-core variations of magnetic properties. Results indicate that there are strong positive relationships between ARM, ARM/SIRM and ARM/ and the fractions finer than 16 m. , SIRM, fd and fd% display relatively weak, but positive correlations with the finer fractions (24 m and 48 m). This suggests that particle size plays an important role in the variation of magnetic properties. Iron species analysis using the BCR method indicates that sediments below 170 cm experienced more reducing environment than that above, which is consistent with the phenomena of stronger reductive diagenesis of magnetic minerals. Ti, an element insensitive to redox conditions, reveals sediment provenance changes in the core CX21. The increase of Ti toward the surface is accompanied by an increase of concentration related magnetic parameters ( and SIRM), suggesting that sediment source is also a main factor influencing magnetic properties. In spite of the difference in sedimentation rate and particle size composition, CX21 and the previously studied core Y7 show similar down core variations of magnetic properties, implying that magnetic properties can be used as a tool for core correlation in area off the Yangtze Estuary.
-
Key words:
- Yangtze Estuary /
- magnetic properties /
- geochemistry /
- particle size /
- sediment source
-
[1] [1] THOMPSON R, OLDFIELD F. Enironmental Magnetism [M]. London: Allen and Unwin, 1986.[2] 朱立平,陈玲,张平中,等. 环境磁学反映的藏南沉错地区1300年来冷暖变化[J]. 第四纪研究, 2001, 21(6): 520-527.[3] 邓成龙,刘青松,潘永信,等. 中国黄土环境磁学[J]. 第四纪研究,2007,27(2):193-209.[4] BIANCHI T S, ALLISON M A. Large-river delta-front estuaries as natural “recorders” of global environmental change [J]. Proceedings of the National Academy of Sciences, 2009, 106: 8085-8092.[5] 覃军干,吴国瑄,郑洪波,等. 从孢粉、藻类化石组合看长江三角洲第一硬质粘土层的成因及古环境意义[J]. 第四纪研究,2004,24(5):546-554.[6] 杨守业,韦刚健,夏小平,等. 长江口晚新生代沉积物的物源研究:REE和Nd同位素制约[J]. 第四纪研究,2007,27(3):339-346.[7] CHEN J F, XIA X M,YE X R, et al. Marine organic pollution history in the Changjiang Estuary and Zhejiang coastal area- HCHs and DDTs stratigraphical records [J]. Marine Pollution Bulletin, 2002, 45: 391-396.[8] 戴仕宝,杨世伦. 近50年来长江水资源特征变化分析[J]. 自然资源学报,2006,21(4):49-58.[9] YANG Z, WANG H, SAITO Y, et al. Dam impacts on the Changjiang River sediment discharge to the sea: the past 55 years and after the Three Gorges Dam[J]. Water Resources Research, 2006, 42, doi: 10.1029/2005WR003970.[10] YANG S L, BELKIN I M, BELKINA A I, et al. Delta response to decline in sediment supply from the Yangtze River: evidence of the recent four decades and expectations for the next half-century [J]. Estuarine, Coastal and Shelf Science, 2003, 57: 689-699.[11] CHEN Z Y, SAITO Y, KANAI Y, et al. Low concentration of heavy metals in the Yangtze estuarine sediments, China: a diluting setting[J]. Estuarine, Coastal and Shelf Science, 2004, 60: 91-100.[12] 杨作升,陈晓辉.近百年来长江口泥质区高分辨率沉积粒度变化及影响因素探讨[J]. 第四纪研究,2007,27(5):690-699.[13] 刘明,范德江. 近60年来长江水下三角洲沉积地球化学记录及其对人类活动的响应[J]. 科学通报,2010,55:3506-3515.[14] 刘莹,翟世奎,李军. 长江口与闽浙沿岸泥质区现代沉积记录及其影响因素[J]. 海洋地质与第四纪地质,2010,30:1-10.[15] 张卫国,贾铁飞,陆敏,等. 长江口水下三角洲Y7柱样磁性特征及其影响因素[J]. 第四纪研究,2007,27(6):1063-1071.[16] 肖尚斌,李安春,将富清,等. 近2ka来东海内陆架泥质沉积物地球化学特征[J]. 地球化学,2010,34(6):595-604.[17] 潘燕俊. 东海近岸泥质区重金属元素的沉积记录[D]. 青岛:中国海洋大学,2008.[18] APPLEBY P G, OLDFIELD F. The calculation of lead-210 dates assuming a constant rate of supply of unsupported 210Pb to the sediment[J]. Catena, 1978(5): 1-8.[19] BLOEMENDAL J, LIU X. Rock magnetism and geochemistry of two Plio-Pleistocene Chinese loess-palaeosol sequences-Implications for quantitative palaeoprecipitation reconstruction [J]. Palaeogeography, Palaeoclimatology, Palaeoecology, 2005, 226(1-2): 149-166.[20] BLOEMENDAL J, KING J W, HALL F R, et al. Rock magnetism of Late Neogene and Pleistocene deep-sea sediments: Relationship to sediment source, diagenetic processes, and sediment lithology[J]. Journal of Geophysical Research, 1992, 97(B4): 4361-4375.[21] 鲁如坤. 土壤农业化学分析方法[M]. 北京:中国农业科技出版社,2000.[22] URE A M, QUEVAUVILLIER P, MUNTAU H, et al. Speciation of heavy metals in soils and sediments: An account of the improvement and harmonization of extraction techniques undertaken under the auspices of the BCR of the commission of the European Communities[J]. International Journal of Environmental Analytical Chemistry, 1993, 51: 135-151.[23] 李海燕,张世红. 黄铁矿加热过程中的矿相变化研究——基于磁化率随温度变化特征分析[J]. 地球物理学报,2005,48(6):1384-1391.[24] MAHER B A. Magnetic properties of some synthetic sub-micron magnetites [J]. Geophysical Journal, 1988, 94(1): 83-96.[25] LIU Q S, ROBERTS A P, TORRENT J, et al. What do the HIRM and S-ratio really measure in environmental magnetism?[J]. Geochemistry Geophysics Geosystems, 2007, doi: 10.1029/2007/GC001717. [26] BANERJEE S K, KING J W, MARVIN J. A rapid method for magnetic granulometry with applications to environmental studies [J]. Geophysical Research Letters, 1981(8): 333-336.[27] FENG H, HAN X F, ZHANG W G, et al. A preliminary study of heavy metal contamination in Yangtze River intertidal zone due to urbanization [J]. Marine Pollution Bulletin, 2004, 49: 910-915.[28] BAKKE J, LIE , HEEGAARD E, et al. Rapid oceanic and atmospheric changes during the Younger Dryas cold period[J]. Nature Geoscience, 2009(2): 202-205.[29] MEYERS P A. Preservation of elemental and isotopic source identification of sedimentary organic matter [J]. Chemical Geology, 1994, 144: 289-302.[30] YUAN C G, SHI J B, HE B, et al. Speciation of heavy metals in marine sediments from the East China Sea by ICP-MS with sequential extraction [J]. Environment International, 2004, 30: 769-783.[31] ZHANG W G, YU L Z. Magnetic properties of tidal flat sediments of the Yangtze Estuary and its relationship with particle size [J]. Science in China (D), 2003, 46: 954-966.[32] KARLIN R, LEVI S. Diagenesis of magnetic minerals in recent haemipelagic sediments [J]. Nature, 1983, 303: 327-330.[33] YAMAZAKI T, ABDELDAYEM A L, IKEHARA K. Rock-magnetic changes with reduction diagenesis in Japan Sea sediments and preservation of geomagnetic secular variation in inclination during the last 30000 years [J]. Earth, Planets and Space, 2003, 55: 327-340.[34] 陈曦. 长江主要输沙支流泥沙性质比较及其对河口沉积物来源判别的指示意义[D]. 上海:华东师范大学,2009.
点击查看大图
计量
- 文章访问数: 2459
- HTML全文浏览量: 34
- PDF下载量: 2038
- 被引次数: 0