中国综合性科技类核心期刊(北大核心)

中国科学引文数据库来源期刊(CSCD)

美国《化学文摘》(CA)收录

美国《数学评论》(MR)收录

俄罗斯《文摘杂志》收录

Message Board

Respected readers, authors and reviewers, you can add comments to this page on any questions about the contribution, review, editing and publication of this journal. We will give you an answer as soon as possible. Thank you for your support!

Name
E-mail
Phone
Title
Content
Verification Code
Issue 5
Sep.  2013
Turn off MathJax
Article Contents
WANG Fei, XU Shao-hui, ZHU Shan-shan, LOU Xue-feng, HUI Ke-shuang, YANG Ping-xiong, WANG Lian-wei. Silver-coated silicon microchannel plates for three-dimensional lithium-ion batteries anodes[J]. Journal of East China Normal University (Natural Sciences), 2013, (5): 110-118, 129.
Citation: WANG Fei, XU Shao-hui, ZHU Shan-shan, LOU Xue-feng, HUI Ke-shuang, YANG Ping-xiong, WANG Lian-wei. Silver-coated silicon microchannel plates for three-dimensional lithium-ion batteries anodes[J]. Journal of East China Normal University (Natural Sciences), 2013, (5): 110-118, 129.

Silver-coated silicon microchannel plates for three-dimensional lithium-ion batteries anodes

  • Received Date: 2012-11-01
  • Rev Recd Date: 2013-02-01
  • Publish Date: 2013-09-25
  • In this work, a three-dimensional (3-D) anode using a silver-coated Si microchannel plate (Si-MCP) as the active materials was prepared by photo-assisted electrochemical etching followed by electroless deposition. Using lithium foils as the counter electrodes, representative half-cells are fabricated and tested. In galvanostatic charge-discharge (C-D) measurements at 10 mAg-1 between 0.02 and 1.5 V, our anode exhibits a charge capacity of 3484.7 mAhg-1 with a coulombic efficiency close to 95.97% in the initial cycle. Based on the cyclicvoltammetry (CV) and the electrochemical impedance spectroscopy (EIS) data, the mechanism about the lithiation of Ag-coated Si-MCP was also studied.
  • loading
  • [1]
    [1] VALVO M, LAFONT U, MUNAO D,et al. Electrospraying-assisted synthesis of tin nanoparticles for Li-ion battery electrodes[J].Journal of Power Sources,2009,189: 297-302.

    [2] SHARMA R A, SEEFURTH R N. Thermodynamic properties of the lithium-silicon system[J].Journal of the Electrochemical Society,1976,123:1763.

    [3] BOUKAMP B A, LESH G C, HUGGINS R A. All-solid lithium electrodes with mixed-conductor matrix[J].Journal of the Electrochemical Society, 1981,128:725.

    [4] ZHAO G Y, MENG Y F, ZHANG N Q, et al. Electrodeposited Si film with excellent stability and high rate performance for lithium-ion battery anodes[J].Materials Letters, 2012,76:55-58.

    [5] CHEN L B, XIE J Y, YU H C, et al. Si-Al thin film anode material with superior cycle performance and rate capability for lithium ion batteries [J].Electrochimica Acta, 2008,53:8149-8153.

    [6] CHAN C K, PENG H L, LIU G, et al. High-performance lithium battery anodes using silicon nanowires[J].Nature Nanotechnology, 2008,3:31. 

    [7] JIA H P, GAO P F, YANG J, et al. Novel Three-Dimensional Mesoporous Silicon for High Power Lithium-Ion Battery Anode Material[J].Advanced Energy Materials, 2011, 1-6:1036-1039.

    [8]  DU N, FAN X, YU J X, et al. Ni3Si2-Si nanowires on Ni foam as a high-performance anode of Li-ion batteries[J].Electrochemistry Communications, 2011,13:1443-1446.

    [9] TIAN M, WANG W, WEI Y J, et al. Stable high areal capacity lithium-ion battery anodes based on three-dimensional Ni-Sn nanowire networks[J].Journal of Power Sources, 2012,211:46.

    [10]  WANG J Z, DU N, ZHANG H, et al. Cu-Si1-xGex core shell nanowire arrays as three-dimensional electrodes for high-rate capability lithium-ion batteries[J].Journal of Power Sources, 2012,208:434.

    [11] XUE L G, FU Z H, YAO Y, et al. Three-dimensional porous Sn-Cu alloy anode for lithium-ion batteries[J]. Electrochimica Acta, 2010,55:7310. 

    [12] WANG C, WANG D L, WANG Q M, et al. Fabrication and lithium storage performance of three-dimensional porous NiO as anode for lithium-ion battery[J].Journal of Power Sources, 2010,195:7432.

    [13]  XUE L J, XU Y F, HUANG L, et al. Lithium storage performance and interfacial processes of three dimensional porous Sn-Co alloy electrodes for lithium-ion batteries[J].Electrochimica Acta, 2011,56:5979.

    [14]  LI X F, DHANABALAN A, GU L, et al. Three-dimensional porous core-shell Sn@carbon composite anodes for high-performance lithium-ion battery applications[J].Advanced Energy Materials, 2012,2:238.

    [15] SUN X, HUANG H, CHU K, et al. Anodized macroporous silicon anode for integration of lithium-ion batteries on chips[J].Journal of Electronic Materials, 2012,41:2369.

    [16] GOLDMAN J L, LONG B R, GEWIRTH A A, et al. Strain anisotropies and self-limiting capacities in single-crystalline 3D silicon microstructures: models for high energy density lithium-ion battery anodes[J].Advanced Functional Materials, 2011,21/23 2412.

    [17] WU X D, WANG Z X, CHEN L Q, et al. Ag-enhanced SEI formation on Si particles for lithium batteries[J]. Electrochemistry Communications, 2003,5: 935-939.

    [18]  CHEN X M, LIN J L, YUAN D, et al. Obtaining a high area ratio free-standing silicon microchannel plate via a modified electrochemical[J].Journal of Micromechanics and Microengineering, 2008,18:037003.

    [19] YUAN D, CI P L, TIAN F, et al. Large-size P-type silicon microchannel plates prepared by photoelectrochemical etching[J].Journal of Micro/Nanolithography, MEMS, and MOEMS, 2009,8:033012.

    [20] 姜晓霞,沈伟.化学镀理论及实践[M].北京:国防工业出版社,2000. 

    [21]  KASAVAJJULA U, WANG C, APPLEBY A J. Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells[J].Journal of Power Sources, 2007,163:1003.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Article views (1930) PDF downloads(2284) Cited by()
    Proportional views

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return