Novel poly(aryl ether quinoxaline)s (PEQs) were prepared via a new two-step procedure. Firstly, poly (ether benzil) (PEB) was synthesized by the polycondensation of 4,4-difluorobenzil and 4,4-isopropylidenediphenol. Then, PEQs were synthesized through chemical modification of PEB by 1,2-diaminobenzene and a small amount of 4,4-oxydibenzene-1,2-diamine(OBDA). The polymers were characterized by IR, NMR, TMA and other measurements. Experiments show that these PEQs can be dissolved in common organic solvents, such as DMF and THF; these PEQs were dissolved in THF to get films which had good transmittance in the visible region (the transmittance was up to 85% at 450 nm). In addition, they also had higher glass transition temperatures (Tg210 ℃), good thermal and mechanical properties, as well as excellent resistance to strong acid and alkali. They are expected to be useful functional materials.